Abstract \\ Ab initio CCSD(full)/6-311++G(3df,2p) calculations were performed for the bimolecular complex NH_3...H_2 and its rearrangements. The ab initio calculations performed predict the existence of sufficiently stable bimolecular complexes NH_3...H_2 with the very small complexation energy of about 0.02 kcal/mol. A peculiar topology of the PES is found around a saddle point of index two.