The FT-IR Spectrum of HC15NO: The nu_1, nu_2, 2 nu_3, and
nu_2 + nu_3 Band Systems

pp. 540-553 (doi:10.1006/jmsp.1993.1200) 

W. Quapp,  S. Albert,  B.P. Winnewisser,  M. Winnewisser  

Univ Leipzig, Inst Math, Augustuspl, O 7010 Leipzig, Germany
Univ Giessen, Inst Phys Chem, W 6300 Giessen, Germany

Abstract

The infrared spectrum of HC15NO an isotopically substituted species of
fulminic acid, has been measured in the range 1900-3600 cm-1 at a resolution
of 0.003 cm-1 with a Bruker IFS 120 HR interferometer. More than 100
subbands have been assigned. Power series coefficients for these transitions
are given. A Coriolis resonance between the levels 01002 (l = 0e) and 01010
(l = 1e) allows normally 'forbidden' transitions to occur, some of which
were observed and assigned. We correlate transition intensities and energies
of the resonance system. Variations in the manifold of n nu_5 states
with excitation of other modes are compared. 

Academic Press